Grafting of (3-Chloropropyl)-Trimethoxy Silane on Halloysite Nanotubes Surface
نویسندگان
چکیده
Modified halloysite nanotubes (HNTs-Cl) were synthesized by a coupling reaction with (3-chloropropyl) trimethoxysilane (CPTMS). The incorporation of chloro-silane onto HNTs surface creates HNTs-Cl, which has great chemical activity and is considered good candidate as an active site that reacts other molecules in order to create new materials applications engineering nanotechnology. value this work lies the fact improving degree grafting HNT’s been accomplished CPTMS under different experimental conditions. Many parameters, such dispersing media, molar ratio HNTs/CPTMS/H2O, refluxing time, type catalyst studied. greatest was using toluene medium for process, HNTs/CPTMS/H2O 1:1:3, time 4 h. addition 7.169 mmol triethylamine (Et3N) 25.97 ammonium hydroxide (NH4OH) led increase surface.
منابع مشابه
Surface Improvement of Halloysite Nanotubes
A novel development on halloysite-polyvinyl alcohol (HNTs-PVA) nanocomposites has been conducted using malonic acid (MA) by crosslinking PVA and HNTs. PVA-MA crosslinking produces smooth surfaces, which play an important role in enhancing the properties of HNTs-PVA nanocomposite. The crystallographic structures of crosslinked HNTs-PVA show almost no change as depicted by the X-ray diffraction (...
متن کامل1 Recent Advances on Surface Modification of 2 Halloysite Nanotubes for Multifunctional 3 Applications 4
Halloysite nanotubes (HNTs) are natural occurring mineral clay nanotubes that have 11 excellent potential application in different fields. However, HNTs are affected by size, surface 12 electron and hydrogen bond formation on the surface which lead to weak affinity and reunion at 13 certain extent. It is very significant to modify the HNTs’ surface to expand its applications. In this 14 review,...
متن کاملGreen synthesis of Au nanoparticles immobilized on halloysite nanotubes for surface-enhanced Raman scattering substrates.
A facile and green route was introduced to synthesize Au nanoparticles immobilized on halloysite nanotubes (AuNPs/HNTs) used for surface-enhanced Raman scattering substrates. The naturally occurring HNTs were firstly functionalized with a large amount of -NH(2) groups by N-(β-aminoethyl)-γ-aminopropyl trimethoxysilane (AEAPTES), which possesses one lone electron pair and will "anchor" Au ions t...
متن کاملDry Sintered Metal Coating of Halloysite Nanotubes
Halloysite nanotubes (HNTs) are a naturally-occurring aluminosilicate whose dimensions measure microns in length and tens of nanometers in diameter. Bonding defects between the alumina and silica lead to net negative and positive charges on the exterior and interior lumen, respectively. HNTs have been shown to enhance the material properties of polymer matrices and enable the sustained release ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Applied sciences
سال: 2021
ISSN: ['2076-3417']
DOI: https://doi.org/10.3390/app11125534